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What is the IR absorption range for double bonds such as: C=C C=O C=N

User Kofyohugna
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Final answer:

The IR absorption ranges are around 1620-1680 cm¹ for C=C, 1650-1750 cm¹ for C=O with key peaks at 1716 cm¹ for ketones, and 1600-1690 cm¹ for C=N, which allows for the identification of these groups using infrared spectroscopy.

Step-by-step explanation:

The IR absorption range for various double bonds is specific to the type of double bond present in the molecule. For example, the carbon-carbon double bond (C=C) typically absorbs in the range of around 1620-1680 cm¹, which is characteristic for alkenes. The carbon-oxygen double bond (C=O), known as a carbonyl group, is highly polar and has a strong absorption, usually in the range of 1650-1750 cm¹, with key peaks around 1716 cm¹ for ketones. This strong peak indicates a powerful dipole change when the bond stretches, making it very noticeable in an infrared spectrum.

The carbon-nitrogen double bond (C=N) is less common and has a variable absorption range, but often appears in the region of 1600-1690 cm¹ depending on the surrounding chemical environment. Infrared spectroscopy is a valuable technique for identifying functional groups within organic compounds based on their characteristic absorption frequencies, and the Spectral Database for Organic Compounds can provide more examples of IR spectra.

User Issa Marie Tseng
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