Final answer:
Calcium chloride (CaCl2) has the highest percent by mass of chlorine.
Step-by-step explanation:
The substance with the highest percent by mass of chlorine is calcium chloride (CaCl2).
To determine this, we need to calculate the percent by mass of chlorine for each substance.
- Sodium chloride (NaCl): This compound has a 1:1 ratio of sodium and chlorine, so the percent by mass of chlorine is 35.45 amu / 58.44 amu x 100% = 60.72%.
- Calcium chloride (CaCl2): This compound has a 1:2 ratio of calcium and chlorine, so the percent by mass of chlorine is (70.90 amu x 2) / 110.98 amu x 100% = 63.65%.
- Hydrochloric acid (HCl): This compound consists of one hydrogen atom and one chlorine atom, so the percent by mass of chlorine is 35.45 amu / 36.46 amu x 100% = 97.00%.
- Chlorine gas (Cl2): This molecule consists of two chlorine atoms, so the percent by mass of chlorine is (35.45 amu x 2) / 70.90 amu x 100% = 100.00%.
Therefore, calcium chloride (CaCl2) has the highest percent by mass of chlorine.