Final answer:
Water has a pH of 7, vinegar is acidic and has a lower pH than water and ammonia, while ammonia is basic and has a higher pH than water and vinegar.
Step-by-step explanation:
The relationship between the pH of water, vinegar, and ammonia is that water has a pH of 7, which is neutral on the pH scale. Vinegar is acidic, with a pH lower than 7, and ammonia is basic, with a pH higher than 7. Therefore, the correct answer is option 2) The pH of vinegar is higher than the pH of water and ammonia.