Final answer:
The molecular shape of HOF is bent, as determined by the VSEPR theory, due to two bonding pairs and two lone pairs on the oxygen atom, leading to a bent molecular geometry despite a tetrahedral electron group geometry.
Step-by-step explanation:
The molecular shape of HOF according to Valence Shell Electron Pair Repulsion (VSEPR) theory is bent. In this molecule, oxygen is the central atom with two bonding pairs (one bond with hydrogen and one with fluorine) and two lone pairs, which leads to a tetrahedral electron group geometry. However, the molecular geometry only considers the positions of the nuclei, not the lone pairs. Therefore, with the two lone pairs effectively pushing the hydrogen and fluorine atoms down, the shape of the molecule is bent or V-shaped.