Final answer:
The '3' outside the brackets in a chemical formula signifies the presence of three of that particular polyatomic ion within the compound.
Step-by-step explanation:
The 3 on the outside of the bracket in a chemical formula indicates how many of that particular polyatomic ion are present in the compound. If a chemical formula has something like (OH)3, this would mean that there are three hydroxide ions in the compound. Each polyatomic ion is surrounded by parentheses to indicate that it is a distinct entity within the compound, and the subscript outside the parentheses tells us the quantity of those ions that combine with the rest of the compound to maintain electrical neutrality.