Final answer:
An ion that is isoelectronic with Ar has the same electron configuration, [Ne]3s²3p⁶. Ions such as K+, Cl−, and S2− are isoelectronic with argon as they all have 18 electrons. Their sizes differ due to variations in nuclear charge.
Step-by-step explanation:
Atoms and ions that have the same electron configuration are said to be isoelectronic. If we are looking for an ion that is isoelectronic with argon (Ar), we need to find an ion that has the same electron configuration as Ar, which is [Ne]3s²3p⁶.
Some ions that are isoelectronic with Ar include K+, Cl−, and S2−, all of which have 18 electrons like Ar. The nuclear charge affects the size of these ions; the greater the nuclear charge, the smaller the ion's radius in a series of isoelectronic ions. Therefore, although K+ (Z = 19), Cl− (Z = 17), and S2− (Z = 16) all have the same number of electrons, their sizes vary due to the different numbers of protons.
Thus, some ions that are isoelectronic with Ar are K+, which has one more proton than Ar, Cl−, which has one fewer proton, and S2−, which has two fewer protons.