Final answer:
Both cellulose and glycogen are polymers of D-glucose, with cellulose connected by β-1,4-glycosidic linkages forming a rigid, linear structure, and glycogen featuring α-1,4-glycosidic and α-1,6-glycosidic linkages, resulting in a highly branched structure for energy storage.
Step-by-step explanation:
Cellulose and glycogen both share the structural feature of being polymers composed of monosaccharides. However, they differ in several ways. Both cellulose and glycogen are polymers of D-glucose, not D-fructose or amylose. The key difference lies in the type of glycosidic linkages that connect the glucose units. Cellulose is connected by β-1,4-glycosidic linkages, forming a linear and highly ordered structure, which allows extensive hydrogen bonding and makes cellulose a rigid component of plant cell walls. On the other hand, glycogen is connected by α-1,4-glycosidic linkages and also has branches with α-1,6-glycosidic linkages, making it a highly branched polymer suitable for rapid energy release in animals.