Final answer:
Ionic solids do not conduct electricity because their ions are fixed in a crystal lattice by strong ionic bonds, preventing movement of charged particles. When melted or dissolved, these bonds break, allowing ions to move freely and thus conduct electricity.
Step-by-step explanation:
An ionic solid like sodium chloride (table salt) does not conduct electricity in its solid form because the ions that make up the solid are locked into a rigid crystal lattice. In this state, the ionic bonds are very strong, which means that the individual ions - the cations and anions - cannot move freely. For a material to conduct electricity, there must be movement of charged particles. As insulators, solid ionic compounds prevent this free movement of ions. However, when an ionic compound melts or dissolves in water, these strong ionic bonds are broken, allowing the individual ions to move freely. This free movement of ions is what allows melted or aqueous solutions of ionic compounds to conduct electricity.