Final answer:
The oxidation states for the compounds in Mn(HSO3)2 are Mn:+2, H:+1, S:+5, O:-2.
Step-by-step explanation:
(a) According to guideline 3, the oxidation number for H is +1.
Using this oxidation number and the compound's formula, guideline 4 may then be used to calculate the oxidation number for sulfur:
(2 x H) + (2 x S) + (6 x O) = 0
2 + 2x + 6(-2) = 0
2 + 2x - 12 = 0
2x - 10 = 0
2x = 10
x = 5
Therefore, the oxidation state of sulfur in Mn(HSO3)2 is +5.
(b) According to guideline 3, the oxidation number for Mn is +2.
Using this oxidation number and the compound's formula, guideline 4 may then be used to calculate the oxidation number for hydrogen:
2 x (1) + (2 x O) = 0
2 + 2x - 4 = 0
2x - 2 = 0
2x = 2
x = 1
Therefore, the oxidation state of hydrogen in Mn(HSO3)2 is +1.
(c) According to guideline 3, the oxidation number for S is +4.
Using this oxidation number and the compound's formula, guideline 4 may then be used to calculate the oxidation number for O:
2 x Mn + 2 x (1) + 2x + (2 x O) = 0
2x + 2 - 2 - 4 = 0
2x - 4 = 0
2x = 4
x = 2
Therefore, the oxidation state of oxygen in Mn(HSO3)2 is -2.
Based on these calculations, the correct oxidation states of each compound in Mn(HSO3)2 are:
Mn: +2, H: +1, S: +5, O: -2.