Final answer:
The substance likely to have a giant ionic structure is option A, which has a high melting point, is insoluble in water, and conducts electricity.
Step-by-step explanation:
The substance that is likely to have a giant ionic structure is option A. It has a high melting point (1400°C), is insoluble in water, and is a good conductor of electricity when solid or molten. These characteristics are typical of a giant ionic structure, where positive and negative ions are arranged in a regular 3D lattice.