Final answer:
Using the Ideal Gas Law, the number of molecules of O2 that occupy a volume of 1.0 L at 65°C and 778 mm Hg is approximately 2.2 x 10^22 molecules.
Step-by-step explanation:
To determine how many molecules of O2 occupy a volume of 1.0 L at 65°C and 778 mm Hg, we can use the Ideal Gas Law, which is PV = nRT. First, we need to convert the given volume to liters, temperature to Kelvin, and pressure to atmospheres.
Volume: Already in liters (1.0 L)
Temperature: 65°C + 273.15 = 338.15 K
Pressure: 778 mm Hg / 760 mm Hg per atm = 1.0237 atm
The Ideal Gas Constant (R) is 0.0821 L·atm/K·mol. Now we can rearrange the Ideal Gas Law to solve for n (number of moles):
n = PV / RT = (1.0237 atm) (1.0 L) / (0.0821 L·atm/K·mol)(338.15 K)
Now, calculate the number of moles and then use Avogadro's number (6.02 x 1023 molecules/mol) to find the number of molecules:
n = 0.0364 moles of O2
Number of molecules = 0.0364 moles * 6.02 x 1023 molecules/mol
Final answer: Approximately 2.2 x 1022 molecules of O2.
So, the correct answer is b) 2.2 x 1022 molecules.