Final answer:
The pair Ca and O is most likely to be part of a polyatomic ion, such as carbonate (CO3^2-) or oxide (O^2-).
Step-by-step explanation:
The pair of elements most likely to be part of a polyatomic ion is d. Ca and O (calcium and oxygen). Calcium and oxygen can combine to form the polyatomic ion known as the carbonate ion (CO32-) in combination with carbon, or the oxide ion (O2-) when found alone. Polyatomic ions are charged entities consisting of multiple atoms bonded together, and they act as a singular charged species when forming compounds. Neither Mn and O, Li and Br, nor K and Cl typically form polyatomic ions as they usually result in the formation of monatomic ions.