Final answer:
Maria Martínez and Julian Martínez created the Black-on-Black Ceramic Vessel in New Mexico in the mid-20th century, which is renowned worldwide.
Step-by-step explanation:
The person who created the Black-on-Black Ceramic Vessel in New Mexico around the mid-20th century CE was none other than the renowned indigenous artist Maria Martínez along with her husband Julian Martínez. Option 3 is the correct answer. Maria Martínez and her husband were both highly skilled potters who developed the black-on-black ceramic technique that became associated with the San Ildefonso Pueblo in New Mexico, and they gained widespread recognition for their work.
Answer: Option 3: Maria Martínez and Julian Martínez