Final answer:
Glycogen is a highly branched polymer of glucose with alpha-1,4-glycosidic bonds linearly and alpha-1,6-glycosidic bonds at branch points about every 8-10 units; starch has less frequent branches or is unbranched.
Step-by-step explanation:
Glycogen structure is a polymer of glucose: a linear chain of alpha-1,4-glycosidic bonds (linear) with alpha-1,6-glycosidic bonds at branch points.
Branch points occur about every 8-10 glucose residues, while starch has branch points every 24-30 glucose residues in the form of amylopectin or is unbranched in the form of amylose.