Final answer:
The first breakthrough band from the UK blues scene was The Rolling Stones, achieving significant international success and becoming iconic figures in rock history.
Step-by-step explanation:
The first breakthrough band to rise from the UK blues scene was c) The Rolling Stones. Formed in London in 1962, The Rolling Stones quickly made a name for themselves with their unique blend of blues and rock and roll, influenced by earlier American genres and artists. They stood out among their peers for their raw energy and charisma, eventually becoming one of the most iconic and enduring bands in rock history. While other bands like John Mayall's Bluesbreakers, Them, and The Yardbirds were also significant in the British blues movement, it's The Rolling Stones that achieved massive international success first, solidifying their place as rock legends.