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what property must change during a molecular vibration in order for that vibrational mode to be Raman-active?

User Adeena
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Final answer:

A Raman-active vibrational mode requires a change in the polarizability of a molecule during vibration.

Step-by-step explanation:

The specific property that must change during a molecular vibration for that vibrational mode to be Raman-active is the polarizability of the molecule. The change in polarizability essentially means that there must be a change in how the electron cloud around a molecule's bond is distorted when exposed to incident light. Unlike infrared activity, which requires a change in the dipole moment, Raman activity depends on the change in polarizability. This is why certain molecular vibrations are only visible in Raman spectroscopy and not in infrared spectroscopy.

User Paul Waldo
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