Final Answer:
The maximum theoretical mass of I₂ that can be produced from the reaction of 0.2829 g of CuSO₄ and 1.0742 g of KI is 0.225 g.
Step-by-step explanation:
Given:
Molar mass of CuSO₄ (M(CuSO₄)) = 159.609 g/mol
Molar mass of KI (M(KI)) = 166.0028 g/mol
Molar mass of I₂ (M(I₂)) = 253.8089 g/mol
Reactant masses:
Mass of CuSO₄ (m(CuSO₄)) = 0.2829 g
Mass of KI (m(KI)) = 1.0742 g
Step 1: Calculate the moles of the reactants
Moles of CuSO₄ (n(CuSO₄)) = m(CuSO₄) / M(CuSO₄) = 0.2829 g / 159.609 g/mol ≈ 0.001777 mol
Moles of KI (n(KI)) = m(KI) / M(KI) = 1.0742 g / 166.0028 g/mol ≈ 0.006468 mol
Step 2: Determine the limiting reactant
Mole ratio = n(CuSO₄) / n(KI) ≈ 0.275
Since the mole ratio is less than 0.5, CuSO₄ is the limiting reactant.
Step 3: Calculate the theoretical yield of I₂
Based on the balanced chemical equation, 2 moles of CuSO₄ react to produce 1 mole of I₂.
Therefore, the theoretical yield of I₂ can be calculated as follows:
n(I₂) = (0.5) × n(CuSO₄) = (0.5) × 0.001777 mol ≈ 0.0008885 mol
Theoretical yield of I₂ (m(I₂)) = n(I₂) × M(I₂) = 0.0008885 mol × 253.8089 g/mol ≈ 0.2253 g
Step 4: Round the answer to the appropriate number of significant figures
The mass of CuSO₄ (0.2829 g) has 4 significant figures.
The mass of KI (1.0742 g) has 5 significant figures.
The molar masses of CuSO₄, KI, and I₂ have 4 significant figures each.
Therefore, the theoretical yield of I₂ should be rounded to 4 significant figures:
Theoretical yield of I₂ (m(I₂)) ≈ 0.2253 g ≈ 0.225 g