SOLUTION
By definition, adjacent angles are (of a pair of angles) formed on the same side of a straight line when intersected by another line.
Vertical Angles are the angles opposite each other when two lines cross.
Going by this above definition, a pair of adjacent angles in the figure in Q1 are:
4 and 2.
Going by this above definition, a pair of vertical angles in the figure in Q1 are:
3 and 2.