Step-by-step explanation
When a balloon is blown up with the human breath, the balloon will increase in its size because there is air inside the balloon. When put in a freezer the size of the balloon will shrink, and this would reduce the size of the balloon.
Recall that, the balloon contains air, and when put in the freezer the temperature will reduce.
According to kinetic molecular theory (KMT), the average kinetic energy is a function of the temperature.
So, when the balloon is put inside the freezer, the temperature of the gas will decrease thereby decreasing the average kinetic energy. This happens because the gas molecules move more slowly and there are fewer collisions of the gas molecules with the inside wall of the balloon