Final answer:
Limestone caves are formed by the process of carbonation, where carbonic acid reacts with calcium carbonate in limestone to create expansive cave systems with features like stalactites and stalagmites. Acid rain has a more pronounced effect on environments rich in limestone, resulting in greater landscape alterations.
Step-by-step explanation:
The process most likely responsible for the formation of limestone caves is chemical weathering, specifically the reaction between carbonic acid and limestone. When water containing dissolved carbon dioxide mixes with the calcium carbonate in limestone, it forms an acidic solution capable of dissolving limestone. This process, known as carbonation, gradually erodes the rock, enlarging fissures and leading to the creation of caves. Over significant periods, typically thousands of years, these actions result in expansive cave systems adorned with stalactites and stalagmites, which are deposits of calcium carbonate precipitated from dripping water inside the caves.
Environmentally, an area rich in limestone would be more affected by acid rain, because the presence of calcium carbonate leads to greater dissolution and potential cave formation when exposed to acidic conditions. This effect is evident in regions known for their karst topography, characterized by distinctive landforms created by the dissolution of soluble rocks like limestone.