Answer:
The smallest possible value of the principal quantum number (n) for an electron in an atom is n = 1. This is referred to as the first energy level or the "1s" orbital, and it corresponds to the lowest energy state of an electron in an atom.
Step-by-step explanation:
In general, the value of n determines the size and energy of the electron orbital. The larger the value of n, the larger the size of the orbital and the higher the energy of the electron. The smallest possible value of n is therefore always 1, and it corresponds to the electron being in its lowest energy state.