They tell us that the pressure of the gas is constant and the temperature and volume vary. If we assume that the gas behaves like an ideal gas, we can apply Charles's law, which tells us:
where,
V1 is the initial volume, 3.62L
T1 is the initial temperature, 21.6°C=294.75K
V2 is the final volume, 3.45L
T2 is the final temperature, in Kelvin
Now, we clear T2 and replace the known data:
The temperature at which the volume of the gas is 3.45 L will be 281K
Answer. b) 281K