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3H2S + 2HNO3 —> 3S + 2NO + 4H2OWhat is being oxidized?What is being reduced?Write the half reaction:

User Ikhsan
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To analyze what is being oxidized and reduced, we need to calcualte the oxidation number of each element.

H₂S and HNO₃ are both acids that have H as the oxidation number 1+. Also, H, in water, H₂O, also has an oxidation number of 1+. So, the hydrogen is neither being oxidized nor reduced.

In all compounds the oxigen is bonded to another element ad its oxidation number is 2- in all of them, HNO₃, NO and H₂O. So, the oxygen is neither being oxidized nor reduced.

In H₂S, the S is bonded with 2 H⁺, so its oxidation number has to be 2- so the compound is neutral. In the right side, S is alone so its oxidation number if 0.

So, each S passed from 2- to 0.

In HNO₃, N is with 3 oxygens 2- and 1 hydrogen 1+. The combined charge of the oxygens and the hydrogen is -5 (-6 from the O and 1+ from H), so the oxidation number of N has to be 5+ for the compound to be neutral.

On the right side, N is only bonded to O 2-, so its oxidation number is 2+.

So, each N passed from 5+ to 2+.

This means that each S lost 2 electrons and each N gained 3 electrons.

Thus, S is being oxidized and N is being reduced.

The half reaction of S is S with charge 2- giving S with charge zero plus 2 electrons:


S^(2-)\rightleftarrows S+2e^-

And the half reaction of N is the 6 H 1+ from HS HNOplus the 3 electrons giving NO and HO.

We can right HNO in its dissociated form:


NO^-_3+4H^++3e^-\rightleftarrows NO+2H_2O_{}

User Xudong Zhang
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