Final answer:
Xenon tetrafluoride (XeF₄) is the xenon compound with a zero dipole moment due to its symmetrical square planar structure which causes the dipole moments to cancel out.
Step-by-step explanation:
The compound of xenon with zero dipole moment is xenon tetrafluoride, or XeF₄. This compound has a square planar structure where the four fluorine atoms are symmetrically placed around the xenon atom at the corners of a square, and the lone pairs of electrons occupy the axial positions. Due to this symmetrical arrangement, the dipole moments cancel each other out, resulting in an overall dipole moment of zero. Xenon difluoride forms when xenon gas reacts with fluorine gas and then cools. It is a stable compound that exists in the form of colorless crystals at room temperature. It has a zero dipole moment because the molecule is linear and the bond dipoles cancel each other out. Other compounds of xenon with fluorine include xenon tetrafluoride (XeF₄) and xenon hexafluoride (XeF₆), which are also stable compounds.