Answer : The mass of Fe and Cl in sample B is 3.341 g and 6.371 g respectively.
Explanation :
Law of definite proportion : It is defined as a given compound always contains exactly the same proportion of elements by weight.
The balanced chemical reaction will be,

First we have to calculate the ratio of mass of
.


Now we have to calculate the mass of Fe and Cl in sample B.


and,


Therefore, the mass of Fe and Cl in sample B is 3.341 g and 6.371 g respectively.