Answer:
Starch has alpha 1,4 linkages to join glucose while cellulose have beta 1,4 linkage to join the glucose molecules together. The different bonding pattern makes starch digestible while cellular indigestible.
Step-by-step explanation:
Starch is a polymer of glucose with alpha 1,4 glycosidic linkage and some alpha 1,6 glycosidic linkages. These alpha bonds are digestible by enzymes present in the human digestive tract. The glycogen (storage sugar of human) also have alpha glycosidic linkages.
On the other hand, cellulose is a polymer of glucose with beta 1,4 glycosidic linkages. These beta glycosidic linkages can not be digested by enzymes of the human digestive system.