Answer:
First, find out how many moles of N2I6 you have. Then convert that to grams.
molar mass N2I6 = 789 g
moles N2I6 = 8.2x1022 molecules N2I6 x 1 mole/6.02x1023 molecules = 1.36x10-1 moles = 0.136 moles
grams N2I6 = 0.136 moles x 789 g/mole = 107 g = 110 g (to 2 significant figures)