Question

What is the pH of a solution that is 0.40 M NaBrO and 0.50 M HBrO (hypobromous acid) (Ka for HBrO = 2.3 x 10^-9)

Answer 1

pH=8.5414

Procedure

The Henderson–Hasselbalch equation relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, Kₐ. In this equation, [HA] and [A⁻] refer to the equilibrium concentrations of the conjugate acid-base pair used to create the buffer solution.

pH = pKa + log₁₀ ([A⁻] / [HA])

Where

pH = acidity of a buffer solution

pKa = negative logarithm of Ka

Ka =acid disassociation constant

[HA]= concentration of an acid

[A⁻]= concentration of conjugate base

First, calculate the pKa

pKa=-log₁₀(Ka)= 8.6383

Then use the equation to get the pH (in this case the acid is HBrO)

`pH=8.6383+\log_(10)(\frac{0.40\text{ M}}{0.50\text{ M}})=8.5414`