Final answer:
The element with a valence electron configuration of 4s^2 is calcium (Ca).
Step-by-step explanation:
The element with a valence electron configuration of 4s2 is calcium (Ca). In the periodic table, calcium is located in Group 2 (alkaline earth metals) and Period 4. Its electron configuration is 1s22s22p63s23p64s2. The valence electrons are the two electrons in the 4s subshell.