C₆H₆ is benzene which has a molar mass of 78 g/mol. When benzene is burned, the reaction is called combustion. The heat produced in this reaction is called the heat of combustion. For benzene, the heat of combustion is -3271 kJ/mol.
Heat of benzene = (8.7 g)(1 mol/78 g)(-3271 kJ/mol) = -364.84 kJ
By conservation of energy,
Heat of benzene = - Heat of water
where
Heat of Water = mCp(Tf - T₀)
where Cp for water is 4.187 kJ/kg·°C
Thus,
-364.84 kJ = -(5691 g)(1 kg/1000 g)(4.187 kJ/kg·°C)(Tf - 21)
Tf = 36.31°C