Step-by-step explanation:
A solution whose constituent particles differ in proportion or when particles are easily separated out then this type of solution is known as heterogeneous solution.
For example, sand in water can be easily separated out as their particles differ in size.
Thus, we can conclude when solid is placed in acetic acid at 16.7 °c, a strong vinegar like odor is noticeable immediately. This system enclosed in the bottle is heterogeneous.