The original blue alien was homozygous dominant (BB). The original green alien was homozygous recessive (bb). ALL of their offspring were Blue, but heterozygous (Bb). The same is true for the 2nd couple, so you mate the offspring (Bb x Bb) and you get the following genotypes: BB, Bb, and bb. 75% will be blue (either BB or Bb) and 25% will be green (BB).
Does this help??