5 to 6 odds means that, out of 11 possible outcomes, odds are that there will be 5 of one kind of outcome and 6 of another kind of outcome.
In this case, you are given 5 to 6 odds, which means that out of 11 possible outcomes you will win a bet 5 times, and lose it 6.
In fraction, it will look like this:
Because of that, the probability of winning the bet is 45.45%, and in a fraction, it is 5/11, which means you will win in 5 out of 11 scenarios.