Let's define:
x: pairs of shoes of Shanice
y: pairs of shoes of Ron
Shanice has 4 times as much many pairs of shoes as does her brother Ron, means:
x = 4y (eq. 1)
If Shanice gives Ron 12 pairs of shoes, she will have twice as many pairs of shoes as Ron does, means:
x - 12 = 2y (eq. 2)
Replacing equation 1 into equation 2:
4y - 12 = 2y
4y - 2y = 12
2y = 12
y = 12/2
y = 6
and
x = 4*6 = 24
After she gives Ron the shoes, she will have left 24-12 = 12 pairs of shoes