Let's convert 5 L to mL. There are a 1000 mL in 1 L. So, clearly, 5 L = 5000 mL. Now, let's add to see how much punch they made in total:

They made 5750 mL in total (her and her brother). Now, to see how many 180 mL servings that is, we can simply divide:

So, they would have 31 servings of 180 mL of punch. There would also be 0.944 of 180 mL left over which is 169.92 mL. All in all, your answer is:
They would have 31 servings of 180 mL, and 169.92 mL left over.