Technetium and Rhodium in the second transition series have four unpaired electrons in their 3+ ions.
Step-by-step explanation:
Electronic Configuration of Tc (Technetium) is
[Kr] 4d⁵, 5s²
And
Electronic Configuration of Tc³⁺ (Technetium) is,
[Kr] 4d⁴
These 4 electrons exist unpaired in d-orbitals, i.e.
↑, ↑, ↑, ↑
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And Electronic Configuration of Rh (Rhodium) is
[Kr] 4d⁸, 5s¹
And
Electronic Configuration of Rh³⁺ is,
[Kr] 4d⁶
Among these 6 electrons, 2 electrons exist in pair while 4 exist unpaired in d-orbitals, i.e.
↑↓, ↑, ↑, ↑, ↑