Answer: Laura needs to ad 64 grams of the chocolate powder, and she knows that each cup of the chocolate powder has 128 grams.
The problem says that she added 2/3 of a cup of chocolate powder to the flour.
If one cup of the powder contains 128g, then 2/3 of a cup contains (2/3)*128g = 85.3g of chocolate powder.
Laura wanted to put 64 g of it, so she went over by (85.3g - 64g) = 21.3g.
You also can see the difference in cups:
if one cup is 128 grams and she wanted to use 64 grams, then she should used half a cup, this is 1/2 cup.
But she used 2/3 cups, then the difference is:
2/3 - 1/2 = 4/6 - 3/6 = 1/6.
So she used 1/6 of a cup more than she should.