Nitrogen fixation is the process by which nitrogen present in the earth,s atmosphere is converted into ammonia or to the interconnected nitrogenous compounds. Nitrogen fixation is important to life because fixed inorganic compounds are essential for the biosynthesis of the nitrogen containing compounds.
Some plants such as legumes have collaborating relationship with the diazotrophic bacteria which fix atmospheric nitrogen into ammonia. These bacteria contain nitrogenase enzyme whici is responsible for biological nitrogen fixation. The reaction for the nitrogen fixation is as follows

The majority of the plants which show symbiotic relationship with the diazotrophic bacteria are legume plants which belongs to Fabacae family.
Since most of the legume plants are grown during the winter season these plants fix nitrogen into suitable nitrates.
Therefore the answer is these crops can fix nitrogen into usable nitrates as most of the legume plants are grown during winter.