Answer:
Say one dice is red in color and the other is yellow. Why do we take two cases (2, 6) and (6, 2)?
Because a 2 on the red one and 6 on the yellow one is different from 2 on the yellow one and 6 on the red one.
In the case of (4, 4), you have 4 on the red one and 4 on the yellow one. How can you have another (4, 4) case? The other one will also be 4 on the red one and 4 on the yellow one.
Explanation: