Final answer:
The molality of the aqueous solution that is 13.5% by mass calcium chloride is approximately 0.979 mol/kg.
Step-by-step explanation:
To calculate the molality of the aqueous solution, we need to first calculate the mass of calcium chloride present in 100 g of the solution. Since the solution is 13.5% by mass calcium chloride, we can calculate:
Mass of calcium chloride = (13.5/100) * 100 g = 13.5 g
Next, we need to calculate the mass of water in the solution. Since the density of the solution is 1.24 g/mL, the mass of 100 mL of solution is 1.24 * 100 = 124 g.
Now, we can calculate the molality using the formula:
Molality = (moles of solute) / (mass of solvent in kg)
moles of calcium chloride = (13.5 g) / (110.98 g/mol) = 0.1213 mol
mass of solvent in kg = (124 g) / 1000 = 0.124 kg
Molality = (0.1213 mol) / (0.124 kg) = 0.979 mol/kg
Therefore, the molality of the solution is approximately 0.979 mol/kg.