Final answer:
To find the pH of the solution of 0.10^-2 M KOH in 10 liters of water, calculate the molarity, then use the water dissociation constant to determine [H3O+], and finally, take the negative log to find the pH, which is 12.
Step-by-step explanation:
To determine the pH of a solution when 0.10-2 mole of KOH is dissolved in 10 litres of water, we first need to calculate the molarity of KOH. Since 0.10-2 moles are dissolved in 10 liters of water, the molarity ([OH-]) is 0.10-2 M.
We use the water dissociation constant (Kw) which at 25 °C is 10-14. The concentration of hydronium ions [H3O+] can be calculated by dividing Kw by the concentration of OH- ions, giving [H3O+] = 10-14 / 0.10-2 M = 10-12 M. Then, to find the pH, we take the negative logarithm (base 10) of the [H3O+], which gives us pH = -log(10-12) = 12.
Therefore, the pH of the solution is 12.