Answer:
Point A' will coincide D and B' will coincide with E.
Explanation:
In the figure attached we have regular octagon ABCDEFGH. It's a regular octagon means all it's sides are equal and central angle of one sector out of 8 sectors formed will be =

Now this octagon is rotated about it's center to form new octagon A'B'C'D'E'F'G'H'
Since angle of rotation is 135° clockwise which means octagon is rotated by 45×3 = 3×(central angle of one sector)
After rotation clockwise new image will coincide like this
A = F'
B = G'
C = H'
D = A'
E = B'
F = C'
G = D'
H = E'
Now we can easily tell that point A' will coincide with the point D of preimage. Similarly point B' of the image will coincide with the point E.