Answer:
The pair that performs second are Orville and Nancy.
Explanation:
Since Jack and Leslie are partners and that they appear before Kelly, it is safe to assume that this pair may come first beforehand in which Orville also comes on before Kelly. Nancy also appears before Leslie and since each pair has a female and a male, it is safe to assume that Orville and Nancy perform second while Jack and Leslie perform first and Kelly and Marty perform last.